Liverpool face Trabzonspor and Aston Villa have Rapid Vienna in the Europa League playoff round.
Roy Hodgson's side will meet the club based in Trabzon, who have won the Turkish league six times, on August 19 and 26.
The play-off is the final hurdle before qualifying for the group stage, with Friday's draw involving 74 clubs.
Trabzonspor won the Turkish cup last season but have not claimed the league title since 1984.
Aston Villa face Rapid Vienna - Austria's most successful club with 32 championships.
The pair met in the same round last season with Villa crashing out of the competition on away goals.
Big-spending Manchester City travel to Romania for the first leg of their play-off after being paired with Timisoara.
The Romanian minnows, established since 2002, finished fifth in their domestic league last season.
Welsh outfit TNS also travel for their first leg, heading to Bulgaria to meet CSKA Sofia.
SPL giants Celtic will take on Dutch side Utrecht.
The Hoops' dropped down to European club football's second tier competition after being knocked out of the Champions League qualifiers by Braga on Wednesday night on a 4-2 aggregate.
Neil Lennon's side, who were seeded for the draw in Nyon, will play the first game at home on August 19 before travelling to Holland a week later.
Motherwell will fancy their chances of making the group stages for the first time after being drawn to play Odense, with the first leg in Denmark.
Craig Brown's men have come through two qualifying rounds against Icelandic side Breidablik and Aalesund.
The Norwegian side were beaten 3-0 at Fir Park on Wednesday as the home side cruised through to the play-offs with a a 4-1 aggregate win.
Dundee United will make their first appearance in the Europa League this season when they take on AEK Athens.
The Active Nation Scottish Cup holders were drawn at home in the first leg and will be looking to take a decent lead to Greece for the return game.
Matches will be played on August 19 and 26.
Lausanne v Lokomotiv Moscow
Gyori v Dinamo Zagreb
Odense v Motherwell
PAOK v Fenerbahce
Villarreal v Dnepr Mogliev
Timisoara v Manchester City
Rapid Vienna v Aston Villa
CSKA Sofia v The New Saints
Besiktas v HJK Helsinki
Slovan Bratislava v Vfb Stuttgart
Sibir Novosibirsk v PSV Eindhoven
BATE v Maritmo
Strum Graz v Juventus
Getafe v APOEL
Dundee United v AEK Athens
AZ Alkmaar v Aktobe
Dnipro v Lech
Grasshopper v Steaua Bucharest
Liverpool v Trabzonspor
Celtic v FC Utrecht
Borussia Dortmund v Qarabag
AIK v Levski
Club Brugge v Dinamo Minsk
AC Omonia v Metalist Kharkiv
Vaslui v Lille
Napoli v IFS Elfsborg
Sporting Club Portugal v Brondby
Genk v Porto
Debrecen v Litex
Aris v Austria Vienna
Galatasary v FC Karpaty
Palermo v NK Maribor
Paris St Germain v M Tel-Aviv
Bayer Leverkusen v Sc Tavriya
CSKA Moscow v Anorthosis
Hajduk Split v FC Unirea
Feyenoord v Gent
I am watching the highlights for the last night match in anfield.
Ngog is hopeless as usual.
But, Stevie is back on fire.
And I have finally see Liverpool smiling and loving the game play.
Hope Ah Roy can keep up the good work of bringing the youngster out at the right time.
Who are Trabzonspor?
Trabzonspor are nicknamed Bordo-Mavililer - the Maroon-Blues.
They play their home games at the Huseyin Avni Aker Stadium, which has a capacity of approximately 20,000.
They've enjoyed great success over the years, winning the Turkish Super League six times, and the Turkish Cup on eight occasions.
Trabzonspor lifted the latter earlier this year after beating Fenerbahce 3-1 in the final, while they claimed a fifth-placed finish in the league.
They are managed by Senol Gunes, who famously led Turkey to third in the 2002 World Cup finals.
Liverpool have met Trabzonspor once before as the two sides clashed in the second round of the 1976-77 European Cup. After losing the first leg 1-0 in Turkey, the Reds ran out comprehensive 3-0 winners in the return meeting thanks to goals from Steve Heighway, David Johnson and Kevin Keegan.
why villa always play the same side in cup comp?? first man u in fa cup now rapid vienna in europa....